We appreciate your concern.
Normally, this really isn't a big problem. When the site is reviewed again, the editor will immediately see that it's already listed in a subcategory, and can immediately delete it. Very little harm done, and no need at all to panic. You aren't going to get a nomination for "spammer of the year" THAT easily.
The submittal guidelines say, "submit to the ONE most appropriate category," but for a legitimate site, our "aggressive spamocide" mode doesn't kick in until well after two submittals. (Of course, ONE submittal of an inappropriate site can trigger spamocide.)